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Design, synthesis and application of a new type of bifunctional Le-Phos in highly enantioselective gamma-addition reactions of N-centered nucleophiles to allenoates
A novel class of cyclic phosphine derived bifunctional catalysts (Le-Phos) is reported, which can be readily prepared from inexpensive and commercially available starting materials and exhibit good performances in enantioselective gamma-addition reactions of N-centered nucleophiles and allenoates under mild conditions. The salient features of this reaction include high product yields, good enantioselectivity, mild reaction conditions, and broad substrate scope and gram-scale scalability.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 2682-49-7 is helpful to your research. Recommanded Product: 2682-49-7
Reference：
Quinuclidine – Wikipedia,
Quinuclidine | C7H417N | ChemSpider