Application In Synthesis of Chalcone. Argouarch, G in [Argouarch, Gilles] Univ Rennes, CNRS, UMR 6226, ISCR, F-35000 Rennes, France published Mild and efficient rhodium-catalyzed deoxygenation of ketones to alkanes in 2019.0, Cited 33.0. The Name is Chalcone. Through research, I have a further understanding and discovery of 94-41-7.
A new and simple method for the deoxygenation of ketones to alkanes is presented. Most substrates are reduced under mild conditions by triethylsilane in the presence of catalytic amounts of [Rh(mu-Cl)(CO)(2)](2). This system selectively provides the methylene hydrocarbons in good to excellent yields starting from acetophenones and diaryl ketones. A rapid examination of the reaction pathway suggests that the ketone is first converted into an alcohol, which then undergoes hydrogenolysis to give the alkane.
Application In Synthesis of Chalcone. About Chalcone, If you have any questions, you can contact Argouarch, G or concate me.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com