Category: thiazolidines. In 2019.0 TETRAHEDRON published article about CATALYZED ALPHA-ALKYLATION; N-HETEROCYCLIC CARBENE; BETA-ALKYLATION; C-C; KETONES; COMPLEXES; AMINES; DEHYDROGENATION; QUINOLINES; PYRIDINES in [Zhang, Shi-Qi; Guo, Bin; Xu, Ze; Li, Hong-Xi; Lang, Jian-Ping] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China; [Li, Hai-Yan] Soochow Univ, Anal & Testing Ctr, Suzhou 215123, Peoples R China in 2019.0, Cited 80.0. The Name is Chalcone. Through research, I have a further understanding and discovery of 94-41-7.
Cobalt(II) complexes (5 mol% Co) bearing phosphine-free N<^>N<^>N pincer ligands efficiently catalyze C-C coupling of secondary and primary alcohols to selectively form alpha-alkylated ketones with a good functional group compatibility using NaOH (20 mol%) as a base at 120 degrees C. The NH group on the N boolean AND N boolean AND N Co(II) precatalyst controls the activity and selectivity. This simple catalytic system is involved in the synthesis of quinolones via the dehydrogenative annulation of 2-aminobenzyl alcohols with secondary alcohols. (C) 2019 Elsevier Ltd. All rights reserved.
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com