Quality Control of Chalcone. I found the field of Chemistry very interesting. Saw the article Diastereoselective sulfonate-directed carbonyl reduction of gamma-keto-sulfonates published in 2019.0, Reprint Addresses Adamo, MFA (corresponding author), Royal Coll Surgeons Ireland, Dept Pharmaceut & Med Chem, CSCB, 123 St Stephens Green, Dublin 2, Ireland.. The CAS is 94-41-7. Through research, I have a further understanding and discovery of Chalcone.
The diastereoselective reduction of gamma-keto-sulfonates to afford alpha,gamma-substituted gamma-hydroxy sulfonates has been investigated. Herein we report the first example of a diastereoselective carbonyl reduction whereby hydride attack is directed via chelation of a neighbouring sulfonate group to a boron atom, thus affording prevalently trans gamma-hydroxy sulfonates. (C) 2019 Published by Elsevier Ltd.
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com