Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Oxidation kinetics of ferrocene derivatives with dibenzoyl peroxide.Recommanded Product: Bromoferrocene.
Chem. oxidation of ferrocene and related derivatives by dibenzoyl peroxide in acetonitrile solution produces ferrocenium and benzoic acid after acidification. The rate law is first order in oxidant and in reductant. Steric effects and activation parameters are consistent with a rate-controlling outer-sphere single-electron transfer (ET) step, and reorganization energies are obtained using Marcus theory with B3LYP calculations Energetics, optimized structures, and solvent effects indicate that rate is affected more by anion than cation solvation and that oxidation of decamethylferrocene by 3-chloroperoxybenzoic acid does not occur by ET.
Here is a brief introduction to this compound(1273-73-0)Recommanded Product: Bromoferrocene, if you want to know about other compounds related to this compound(1273-73-0), you can read my other articles.
Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com