Category: 1273-73-0

Application of 1273-73-0. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Stochastic detection and characterisation of individual ferrocene derivative tagged graphene nanoplatelets. Author is Wu, Haoyu; Lin, Qianqi; Batchelor-McAuley, Christopher; Goncalves, Luis Moreira; Lima, Carlos F. R. A. C.; Compton, Richard G..

Graphene nanoplatelets (GNPs) are ‘tagged’ with 1-(biphen-4-yl)ferrocene. Chronoamperometry is then utilized to observe single particle impacts when GNPs suspended in solution collide with a carbon fiber micro wire electrode held at an oxidizing potential, resulting in current/time transient “”spikes””. The impacts are associated with two types of charge transfer: Faradaic due to oxidation of the ‘tag’ and capacitative due to disruption of the double layer. Anal. of the spikes suggests approx. monolayer coverage of 1-(biphen-4-yl)ferrocene on the GNP surfaces, with a surface coverage of (2.2 ± 0.3) × 10-10 mol cm-2. In contrast non-derivatized ferrocene does not exhibit any significant adsorption on the GNP material.

When you point to this article, it is believed that you are also very interested in this compound(1273-73-0)Application of 1273-73-0 and due to space limitations, I can only present the most important information.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com

Perevalova, E. G.; Lemenovskii, D. A.; Grandberg, K. I.; Nesmeyanov, A. N. published the article 《Action of halogens on ferrocenylgold-triphenylphosphine》. Keywords: ferrocenyl gold phosphine bromination.They researched the compound: Bromoferrocene( cas:1273-73-0 ).Safety of Bromoferrocene. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:1273-73-0) here.

Ph3P.AuC5H4FeC5H5 (I) brominated in CCl4 at -20° to a blue, then yellow material and after evaporation gave 55% bromoferrocene and 18% biferrocenyl along with 70% Ph3P.AuBr. Similar results were obtained at -50° in CH2Cl2. I chlorinated as above to 26% chloroferrocene, 70% biferrocenyl, and 98% Ph3P.AuCl. Iodination gave 82% iodoferrocene and 89% Ph3P.AuI.

When you point to this article, it is believed that you are also very interested in this compound(1273-73-0)Safety of Bromoferrocene and due to space limitations, I can only present the most important information.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com

Synthetic Route of C10BrFe. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Surface Functionalization of a γ-Graphyne-like Carbon Material via Click Chemistry.

Surface functionalization of carbon materials is of interest in many research fields, such as electrocatalysis, interfacial engineering, and supercapacitors. As an emerging carbon material, γ-graphyne has attracted broad attention. Herein, we report that the surface functionalization of a γ-graphyne-like carbon material (γ-G1) is achieved by immobilizing functional groups via the click chem. Texture anal. of aberration-corrected microscopy, XPS, and electrochem. confirm the successful surface modification of γ-G1 through a strong covalent linkage 1,2,3-triazole. The direct linkage of functional groups on γ-G1 via the click chem. represents a general method for preparing other functional materials by using γ-graphyne-like materials as a skeleton.

When you point to this article, it is believed that you are also very interested in this compound(1273-73-0)Synthetic Route of C10BrFe and due to space limitations, I can only present the most important information.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Electroanalysis called Ferrocene Aryl Derivatives for the Redox Tagging of Graphene Nanoplatelets, Author is Yang, Minjun; Batchelor-McAuley, Christopher; Moreira Goncalves, Luis; Lima, Carlos F. R. A. C.; Vyskocil, Vlastimil; Tschulik, Kristina; Compton, Richard G., which mentions a compound: 1273-73-0, SMILESS is Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25, Molecular C10BrFe, Synthetic Route of C10BrFe.

Aryl derivatives of ferrocene were used for the modification of graphitic surfaces. Stronger adsorption was used as a route to enable the electrochem. tagging of new C materials. Model experiments are reported on an EPPG electrode where the adsorption of 1-(biphen-4-yl)ferrocene is a factor of ∼5 times more thermodynamically favorable than the underivatised form. Two further derivatives were also studied and the voltammetric responses of this class of ferrocenes are significantly influenced by ion-pairing. Finally, the successful use of these new materials for the modification and redox tagging of graphene nanoplatelets is demonstrated.

When you point to this article, it is believed that you are also very interested in this compound(1273-73-0)Synthetic Route of C10BrFe and due to space limitations, I can only present the most important information.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Sato, Masaru; Motoyama, Izumi; Hata, Kazuo researched the compound: Bromoferrocene( cas:1273-73-0 ).Formula: C10BrFe.They published the article 《Reactions of haloferrocenes. II. Kinetic studies of the reaction of haloferrocene with copper(1) chloride-pyridine complex》 about this compound( cas:1273-73-0 ) in Bulletin of the Chemical Society of Japan. Keywords: bromo ferrocenes halogen exchange; halogen exchange bromo ferrocenes; ferrocenes bromo halogen exchange. We’ll tell you more about this compound (cas:1273-73-0).

The reaction of bromoferrocene with CuCl-C5H5N complex was second-order; first-order in each of bromoferrocene and CuCl-C5H5N. Competitive reactions between bromoferrocene and PhBr indicated that bromoferrocene was 103 times more reactive than PhBr in the halogenexchange reaction. The effects of pyridine bases on the halogen-exchange reaction of bromoferrocene were examined, and the trend of results was different from that of PhBr.

As far as I know, this compound(1273-73-0)Formula: C10BrFe can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Journal of Organometallic Chemistry called Ferrocenylamines, Author is Herberhold, Max; Ellinger, Max; Kremnitz, Walter, which mentions a compound: 1273-73-0, SMILESS is Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25, Molecular C10BrFe, Quality Control of Bromoferrocene.

A general method for the preparation of ferrocenylamines involves the reactions of ferrocenyl bromide, FcBr, with the Na salt of an amine or amide in the presence of copper(I) bromide/pyridine. The syntheses of diferrocenylphenylamine and triferrocenylamine, NFc2Ph and NFc3, resp., are reported, and the hydrolysis of N-ferrocenylacetamide to give ferrocenylamine, NH2Fc, is described. The system of the ferrocenyl- and/or phenyl-substituted derivatives of ammonia, NFcnX3-n (n = 0-3; X = H, Ph), is characterized on the basis of mass, UV, visible, and 1H and 13C NMR spectra.

As far as I know, this compound(1273-73-0)Quality Control of Bromoferrocene can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com

The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Diferrocenylamine》. Authors are Nesmeyanov, A. N.; Sazonova, V. A.; Romanenko, V. I..The article about the compound:Bromoferrocenecas:1273-73-0,SMILESS:Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25).Recommanded Product: 1273-73-0. Through the article, more information about this compound (cas:1273-73-0) is conveyed.

N-Acetylferrocenylamine heated with excess EtONa 40 min. at 150° gave a red-brown Na derivative, which with bromoferrocene in the presence of CuBr 1 h. at 110-20° gave a mixture of ferrocene, diferrocenyl, azoferrocene, starting material, and some N-acetyldiferrocenylamine, m. 176° (heptane). This and LiAlH4 in Et2O 6 h. gave after an aqueous treatment 8.3% N-ethyldiferrocenylamine, m. 149-9.5°, and yellow (70%) diferrocenylamine, m. 152-3° (aqueous EtOH). This and Et3O+BF4- 5-10 min. at room temperature gave 56% ethyldiferrocenylamine, identical with the above. N-Benzoylferrocenylamine in THF added to LiAlH4 and refluxed 6 h. under N gave after an aqueous treatment 86% benzylferrocenylamine, m. 125°; benzoyl derivative m. 134.5-5.5°. The amine and Et3O+BF4- in CH2Cl2 gave in 5 min. refluxing 81% ethylbenzylferrocenylamine, m. 48-8.5°. N-Acetylferrocenylamine was reduced with LiAlH4 in Et2O to 94% ethylferrocenylamine m. 56.5-8°, identical with the specimen formed from ferrocenylamine and Et3O+BF4-.

As far as I know, this compound(1273-73-0)Recommanded Product: 1273-73-0 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com

Related Products of 1273-73-0. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Energy barrier to internal rotation in some ferrocene derivatives from dielectric measurements. Author is Sorriso, Salvatore.

Dipole moments have been measured in n-decane at 5-130° for the compounds monochloro-, 1,1′-dichloro-, monobromo-, 1,1′-dibromo-, monoiodo-, and 1,1′-diiodoferrocene. The energy barriers to rotation of the two cyclopentadiene rings about the bond to iron have been calculated Free rotation exists in the parent mol., ferrocene. Steric effects between the halo substituents of one ring and the H atoms of the other ring are small.

As far as I know, this compound(1273-73-0)Related Products of 1273-73-0 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com

SDS of cas: 1273-73-0. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Reactions of haloferrocenes. III. Reaction of haloferrocenes with copper(I) benzenethiolate, thiocyanate, acetate, and benzoate. Author is Sato, Masaru; Motoyama, Izumi; Hata, Kazuo.

Iodoferrocene reacted with copper(I) benzenethiolate in boiling pyridine to give ferrocenyl Ph sulfide in a quant. yield. The reaction of iodoferrocene with copper(I) thiocyanate gave diferrocenyl disulfide. The behavior of copper(I) acetate and benzoate toward haloferrocene was different from those of the other copper(I) salts: reactions in boiling pyridine gave the corresponding ferrocenyl ester, together with a small quantity of ferrocene, while the reaction in boiling toluene produced biferrocenyl as the main product. The reaction mechanism of the ferrocenyl ester and biferrocenyl formations was discussed.

As far as I know, this compound(1273-73-0)SDS of cas: 1273-73-0 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Rajput, Jaisheila; Moss, John R.; Hutton, Alan T.; Hendricks, Denver T.; Arendse, Catherine E.; Imrie, Christopher researched the compound: Bromoferrocene( cas:1273-73-0 ).Electric Literature of C10BrFe.They published the article 《Synthesis, characterization and cytotoxicity of some palladium(II), platinum(II), rhodium(I) and iridium(I) complexes of ferrocenylpyridine and related ligands. Crystal and molecular structure of trans-dichlorobis(3-ferrocenylpyridine)palladium(II)》 about this compound( cas:1273-73-0 ) in Journal of Organometallic Chemistry. Keywords: ferrocenyl pyridine preparation redox potential reaction Group VIII complex; palladium ferrocenylpyridine complex preparation structure cyclic voltammetry human cytotoxicity; platinum pyridinylferrocene chloro complex preparation human cytotoxicity; iridium rhodium pyridylferrocene complex human cytotoxicity structure activity relationship; crystal structure palladium ferrocenylpyridine chloro complex; mol structure palladium ferrocenylpyridine chloro complex. We’ll tell you more about this compound (cas:1273-73-0).

The preparation of a series of ferrocenyl nitrogen donor ligands including ferrocenylpyridines, ferrocenylphenylpyridines and 1,1′-di(2-pyridyl)ferrocene is described. Coordination studies of the substituted pyridines (L) were carried out with platinum, palladium, rhodium and iridium. This resulted in the preparation of the following types of complexes: [MCl(CO)2(L)] and [M(cod)(L)2]ClO4 where M = Rh or Ir, cod = 1,5-cyclooctadiene; [M’Cl2(L)2] where M’ = Pt or Pd. The X-ray crystal structure of trans-dichlorobis(3-ferrocenylpyridine)palladium was obtained. The complexes were screened for activity against two human cancer cell lines. At least two of the complexes displayed growth inhibition similar to that of the widely used chemotherapeutic agent, cisplatin.

As far as I know, this compound(1273-73-0)Electric Literature of C10BrFe can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com