Category: 78-39-7

In 2019.0 ANGEW CHEM INT EDIT published article about ENE REACTION; EFFICIENT SYNTHESIS; CARBON-CARBON; BENZYNE; CONSTRUCTION; PRECURSOR; CYCLOADDITIONS; DIAMINATION; ACTIVATION; GENERATION in [He, Jia; Jia, Zizi; Tan, Hongcheng; Luo, Xiaohua; Qiu, Dachuan; Shi, Jiarong; Xu, Hai; Li, Yang] Chongqing Univ, Sch Chem & Chem Engn, 174 Shazheng St, Chongqing 400030, Peoples R China in 2019.0, Cited 75.0. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7. SDS of cas: 78-39-7

A convenient and efficient domino aryne process was developed under transition-metal-free conditions to generate a range of tetra- and pentacyclic ring systems. This transformation was realized via a 1,2-benzdiyne through a nucleophilic and Diels-Alder reaction cascade using styrene as the diene moiety. Three new chemical bonds, namely one C-N and two C-C bonds, and two benzofused rings could be constructed concomitantly, which was made possible by distinct chemoselective control at both the 1,2-aryne and 2,3-aryne stages. Moreover, in-depth studies were carried out on the domino aryne precursors and controlling the diastereoselectivity.

SDS of cas: 78-39-7. Welcome to talk about 78-39-7, If you have any questions, you can contact He, J; Jia, ZZ; Tan, HC; Luo, XH; Qiu, DC; Shi, JR; Xu, H; Li, Y or send Email.

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An article Iridium-Catalyzed gamma-Selective Hydroboration of gamma-Substituted Allylic Amides WOS:000526335800069 published article about TERTIARY BORONIC ESTERS; ASYMMETRIC HYDROBORATION; ENANTIOSELECTIVE HYDROBORATION; ALKENE HYDROBORATION; CARBONYL-COMPOUNDS; BETA-BORATION; BORYLATION; HYDROFUNCTIONALIZATION; AZETIDINES; SECONDARY in [Zhao, Hongliang; Zhang, Panke] Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Henan Adv Inst Technol, Zhengzhou 450001, Henan, Peoples R China; [Zhao, Hongliang; Gao, Qian; Zhang, Yajuan; Xu, Senmiao] Chinese Acad Sci, Ctr Excellence Mol Sci, Suzhou Res Inst, Lanzhou Inst Chem Phys,State Key Lab Oxo Synth &, Lanzhou 730000, Gansu, Peoples R China; [Xu, Senmiao] Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Peoples R China; [Xu, Senmiao] Univ Chinese Acad Sci, Beijing 100049, Peoples R China in 2020.0, Cited 84.0. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7. Category: thiazolidines

Reported here for the first time is the Ir-catalyzed gamma-selective hydroboration of gamma-substituted allylic amides under mild reaction conditions. A variety of functional groups could be compatible with reaction conditions, affording gamma-branched amides in good yields with <= 97% gamma-selectivity. We have also demonstrated that the obtained borylated products could be used in a series of C-O, C-F, C-Br, and C-C bond-forming reactions. Category: thiazolidines. About 1,1,1-Triethoxyethane, If you have any questions, you can contact Zhao, HL; Gao, Q; Zhang, YJ; Zhang, PK; Xu, SM or concate me.

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An article Microwave-assisted synthesis of l-histidine capped silver nanoparticles for enhanced photocatalytic activity under visible light and effectual antibacterial performance WOS:000480558400036 published article about GREEN SYNTHESIS; GOLD NANOPARTICLES; MGO NANOCOMPOSITE; ANIONIC DYES; EXTRACT; BIOSYNTHESIS; DEGRADATION; MEMBRANE; GRAPHENE; CHITOSAN in [Suganthi, Sanjeevamuthu; Mohanapriya, Subramanian; Raj, Vairamuthu] Periyar Univ, Dept Chem, Adv Mat Res Lab, Salem 636011, Tamil Nadu, India; [Vignesh, Shanmugam; Sundar, Jeyaperumal Kalyana] Periyar Univ, Mat Sci Res Lab, Dept Phys, Salem 636011, Tamil Nadu, India in 2019.0, Cited 72.0. Product Details of 78-39-7. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7

A facile, rapid one-step green strategy is established here to prepare the l-Histidine (His) capped silver nanoparticles (His-AgNPs) using microwave irradiation conditions performed for optimal duration of 5 min. For the prepared His-AgNPs have been characterized by X-ray powder diffraction spectroscopy (XRD), Fourier transform infrared spectroscopy (FTIR), high-resolution scanning electron microscopy (HR-SEM), Zeta potential measurements and high-resolution transmission electron microscopy (HR-TEM), Energy dispersive X-ray spectroscopy (EDX) and UV-Vis spectroscopy techniques also. The HR-SEM images have exposed that flake-like internal structure formation of His-AgNPs with sort nanometer-sized spherical shape morphology has attained. As well, studies prove that, the antibacterial activities of synthesized His-AgNPs had a significant performance against various G(+) and G(-) bacteria. Then, the photocatalytic actions of His-AgNPs seem to contain sustaining degradation of MB and MO aqueous dyes under visible light exposure. Overall, the 98% of cationic MB dye degraded within 40 min and 97% anionic MO dye degraded within 100 min of photocatalytic irradiation. The probable mechanism for the improved photocatalytic assets of the His-AgNPs is also discussed. Hence, this study validated a simple and economical approach to synthesize His-AgNPs that are potential candidates for various highly useful industrial and packaging applications.

Welcome to talk about 78-39-7, If you have any questions, you can contact Suganthi, S; Vignesh, S; Mohanapriya, S; Sundar, JK; Raj, V or send Email.. Product Details of 78-39-7

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Authors Koziol, A; Fratczak, J; Grela, E; Szczepanik, M; Gabrys, B; Dancewicz, K; Lochynski, S in TAYLOR & FRANCIS LTD published article about NATURAL-PRODUCTS; STEREOCHEMISTRY in [Koziol, Agata; Fratczak, Jakub; Grela, Ewa; Lochynski, Stanislaw] Wroclaw Univ Sci & Technol, Fac Chem, Dept Bioorgan Chem, Wroclaw, Poland; [Koziol, Agata; Lochynski, Stanislaw] Acad Physiotherapy Wroclaw, Inst Cosmetol, Wroclaw, Poland; [Szczepanik, Maryla] Nicolaus Copernicus Univ, Dept Invertebrate Zool, Torun, Poland; [Gabrys, Beata; Dancewicz, Katarzyna] Univ Zielona Gora, Fac Biol Sci, Dept Bot & Ecol, Zielona Gora, Poland in 2020.0, Cited 16.0. SDS of cas: 78-39-7. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7

Terpenoid derivatives, which contain a preserved carane system in their structure, exhibit a broad spectrum of biological activities. Among them, we can distinguish insecticides, structures with pharmacological application etc. In the presented paper, the substrate – (-)-cis-caran-trans-4-ol was transformed using the reactions of typical organic synthesis to obtain novel derivatives. Most importantly, bromolactone ((-)-(1R,4R,6S)-2′-(bromomethyl)-4,7,7-trimethylspiro[bicyclo[4.1.0]heptan-3,3′-furan]-5′(4’H)-one) with the preserved carane system was synthesized. This bromolactone was tested for antifeedant activity against the lesser mealworm, Alphitobius diaperinus Panzer, and peach potato aphid (Myzus persicae). In addition, its moderate antibacterial activity was observed against the Bacillus subtilis strain (with Minimal Inhibitory Concentration of 200 mu g/mL).

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Recently I am researching about MEDICINAL CHEMISTS, Saw an article supported by the EPSRCUK Research & Innovation (UKRI)Engineering & Physical Sciences Research Council (EPSRC) [EP/N025652/1]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Leggott, A; Clarke, JE; Chow, S; Warriner, SL; O’Neill, AJ; Nelson, A. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane. Product Details of 78-39-7

The feasibility of using activity-directed synthesis to drive antibacterial discovery was investigated. An array of 220 Pd-catalysed microscale reactions was executed, and the crude product mixtures were evaluated for activity againstStaphylococcus aureus.Scale-up of the hit reactions, purification and evaluation, enabled expansion of a class of antibacterial quinazolinones. The novel antibacterials had MICs from 0.016 mu g mL(-1)(i.e.38 nM) to 2-4 mu g mL(-1)againstS. aureusATCC29213.

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Recently I am researching about TRIAZOLE; COMPLEXES; PYRAZOLE, Saw an article supported by the Kuwait University [SC 05/17]; RSPU [GS 03/08, GS 01/01, GS 01/03, GS 01/05]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Al-Azmi, A; Mahmoud, H. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane. Computed Properties of C8H18O3

A group of novel 1,4-bis(3,5-dialkyl-4H-1,2,4-triazol-4-yl)bencene and 5-aryltriaz- 1-en-1-yl-1-phenyl-1H-pyrazole-4-carbonitrile derivatives have been successfully synthesized and characterized by spectroscopic analyses. The triazenes were obtained in moderate yield by a coupling reaction between 5-aminopyrazol-4-carbonitrile and aryl diazonium chlorides, and their structures were confirmed by detecting the CN functional group in both IR and C-13 NMR spectra. Conversely, the novel 1,4-bis(3,5-dialkyl-4H-1,2,4-triazol-4-yl)benzene derivatives were obtained using a previously unreported and facile pathway starting with p-phenylenediamine with selected triethyl orthoalkylates and then hydrazine monohydrate, followed by refluxing in triethyl orthoalkylates. The structure of the methyl derivative was confirmed by X-ray analysis. The synthesized compounds were tested and evaluated as antimicrobial agents.

Computed Properties of C8H18O3. Welcome to talk about 78-39-7, If you have any questions, you can contact Al-Azmi, A; Mahmoud, H or send Email.

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An article The first in situ synthesis of 1,3-dioxan-5-one derivatives and their direct use in Claisen-Schmidt reactions WOS:000471188200001 published article about DE-NOVO SYNTHESIS; BLOCK in [Mojtahedi, Mohammad M.; Abaee, M. Saeed] Chem & Chem Engn Res Ctr Iran, Organ Chem Dept, POB 14335-186, Tehran, Iran; [Poursharifi, M. Javad] Islamic Azad Univ, Dept Chem, Sci & Res Branch, Tehran 1477893855, Iran; [Hashemi, Mohammad M.] Sharif Univ Technol Tehran, Fac Chem, Dept Organ Chem, Tehran 113658639, Iran in 2019.0, Cited 34.0. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7. Safety of 1,1,1-Triethoxyethane

A method is developed for in situ generation of 1,3-dioxan-5-one derivatives 2. These compounds are simple precursors for accessing carbohydrate structures and previously had to be produced via stepwise procedures using excessive amounts of reagents. In the present work, three different derivatives of 2 were synthesized via the reaction of trialkoxyalkanes with dihydroxyacetone dimer 1 in the presence of acetic acid as the catalyst. In the same pot, derivatives of 2 were reacted with aromatic aldehydes and 30 mol% of pyrrolidine to obtain high yields of the respective bischalcones 3 within short time periods.

Welcome to talk about 78-39-7, If you have any questions, you can contact Poursharifi, MJ; Mojtahedi, MM; Abaee, MS; Hashemi, MM or send Email.. Safety of 1,1,1-Triethoxyethane

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Category: thiazolidines. Authors Hajri, A; Marzouki, L in MAIK NAUKA/INTERPERIODICA/SPRINGER published article about in [Hajri, A.; Marzouki, L.] Univ Jendouba, Higher Inst Biotechnol Beja, Lab Funct Physiol & Valuat Bioresources UR17ES27, Beja, Tunisia in 2019.0, Cited 8.0. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7

The condensation of 4H-1,2,4-triazol-3-amine with ortho esters derived from acetic, propionic, and benzoic acids gave the corresponding N-(4H-1,2,4-triazol-3-yl) carboximidates which were treated with cyanamide, carbon disulfide, and sodium thiocyanate to afford 7-substituted [1,2,4]triazolo[4,3-a][1,3,5]triazin-5-amines, [1,2,4]triazolo[4,3-c][1,3,5]thiadiazine-5-thiones, and [1,2,4]triazolo[4,3-c][1,3,5]thiadiazin-5-imines, respectively. The structures of the synthesized compounds were confirmed by IR, H-1 and C-13 NMR, and mass spectra and elemental analyses.

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Safety of 1,1,1-Triethoxyethane. I found the field of Chemistry very interesting. Saw the article Lewis Base/Bronsted Acid Co-Catalyzed Asymmetric Thiolation of Alkenes with Acid-Controlled Divergent Regioselectivity published in 2019.0, Reprint Addresses Chen, ZM (corresponding author), Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai Key Lab Mol Engn Chiral Drugs, 800 Dongchuan Rd, Shanghai 200240, Peoples R China.; Liu, YY (corresponding author), East China Normal Univ, Sch Chem & Mol Engn, 500 Dongchuan Rd, Shanghai 200241, Peoples R China.. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane.

A divergent strategy for the facile preparation of various enantioenriched phenylthio-substituted lactones was developed based on Lewis base/Bronsted acid co-catalyzed thiolation of homoallylic acids. The acid-controlled regiodivergent cyclization (6-endo vs. 5-exo) and acid-mediated stereoselective rearrangement of phenylthio-substituted lactones were explored. Experimental and computational studies were performed to clarify the origins of the regioselectivity and enantioselectivity. The calculation results suggest that C-O and C-S bond formation might occur simultaneously, without formation of a commonly supposed catalyst-coordinated thiiranium ion intermediate and the potential pi-pi stacking between substrate and SPh as an important factor in the enantio-determining step. Finally, this methodology was applied in the rapid syntheses of the bioactive natural products (+)-ricciocarpin A and (R)-dodecan-4-olide.

Safety of 1,1,1-Triethoxyethane. Welcome to talk about 78-39-7, If you have any questions, you can contact Luo, HY; Dong, JW; Xie, YY; Song, XF; Zhu, D; Ding, TM; Liu, YY; Chen, ZM or send Email.

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Name: 1,1,1-Triethoxyethane. In 2019.0 J ENZYM INHIB MED CH published article about GROWTH-FACTOR RECEPTOR; NATIONAL-CANCER-INSTITUTE; DRUG DISCOVERY; BREAST-CANCER; IN-VITRO; EXPRESSION; SURVIVAL; THERAPY; ASSAY in [Maher, Mai; Kassab, Asmaa E.; Zaher, Ashraf F.; Mahmoud, Zeinab] Cairo Univ, Dept Organ Pharmaceut Chem, Fac Pharm, Cairo 11562, Egypt in 2019.0, Cited 36.0. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7.

A series of novel pyrazolo[3,4-d]pyrimidines was synthesised. Twelve synthesised compounds were evaluated for their anticancer activity against 60 human tumour cell lines by NCI (USA). Compound 7d proved prominent anticancer activity. It showed 1.6-fold more potent anti-proliferative activity against OVCAR-4 cell line with IC50 = 1.74 mu M. It also exhibited promising potent anticancer activity against ACHN cell line with IC50 value 5.53 mu M, representing 2.2-fold more potency than Erlotinib. Regarding NCI-H460 cell line, compound 7d (IC50 = 4.44 mu M) was 1.9-fold more potent than Erlotinib. It inhibited EGFR and ErbB2 kinases at sub-micromolar level (IC50 = 0.18 and 0.25 mu M, respectively). Dual inhibition of EGFR and ErbB2 caused induction of apoptosis which was confirmed by a significant increase in the level of active caspase-3 (11-fold). It showed accumulation of cells in pre-G1 phase and cell cycle arrest at G2/M phase.

Name: 1,1,1-Triethoxyethane. Welcome to talk about 78-39-7, If you have any questions, you can contact Maher, M; Kassab, AE; Zaher, AF; Mahmoud, Z or send Email.

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