Recently I am researching about ENANTIOSELECTIVE TOTAL SYNTHESES; MITSUNOBU REACTION; AKUAMMILINE ALKALOIDS; INDOLE ALKALOIDS; FORMAL SYNTHESIS; (+)-ASPIDOSPERMIDINE; REARRANGEMENT, Saw an article supported by the National Science Foundation of China (NSFC)National Natural Science Foundation of China (NSFC) [21672181/21272199]; Research Grants Council (Hong Kong) (RGC)Hong Kong Research Grants Council [CUHK14309216/CUHK14303815/403012]; NSFC/RGC Joint Research SchemeNational Natural Science Foundation of China (NSFC) [N_CUHK451/13]; Shenzhen Science and Technology Innovation Committee [JCYJ20160608151520697]; Ministry of Science and Technology (China)Ministry of Science and Technology, China; Innovation and Technology Commission’s Guangdong-Hong Kong Technology Cooperation Funding Scheme [GHP/004/16GD]; Chinese Academy of Sciences-Croucher Foundation; Chinese University of Hong KongChinese University of Hong Kong [4053325]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Zhou, YG; Wong, HNC; Peng, XS. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane. Computed Properties of C8H18O3
The total syntheses of Aspidosperma and Kopsia alkaloids (-)-deoxoapodine, (-)-kopsifoline D, and (-)-beninine are described through a domino deprotection-Michael addition-nucleophilic substitution protocol to assemble the core framework in efficient steps. Corey-Bakshi-Shibata reduction was employed to afford the enantioenriched intermediate for the total syntheses of the aforementioned alkaloids. The chirality was shown to completely transfer to the backbone using Johnson-Claisen rearrangement. The enantioselective total syntheses of (-)-kopsifoline D and (-)-beninine were accomplished for the first time. Our strategy opens up practical avenues for the total synthesis of structurally similar alkaloids.
Computed Properties of C8H18O3. Bye, fridends, I hope you can learn more about C8H18O3, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com