Recently I am researching about DENSITY-FUNCTIONAL THERMOCHEMISTRY; TERMINAL ALKYNES; ETHYL LACTATE; EFFICIENT; PERTURBATION; DERIVATIVES; COMPLEXES; ALDEHYDES; KETONES, Saw an article supported by the DST-SERBDepartment of Science & Technology (India)Science Engineering Research Board (SERB), India; C.S.I.RCouncil of Scientific & Industrial Research (CSIR) – India; U.G.C., New DelhiUniversity Grants Commission, India. Published in ELSEVIER in AMSTERDAM ,Authors: Dandia, A; Saini, P; Chithra, MJ; Vennapusa, SR; Parewa, V. The CAS is 94-41-7. Through research, I have a further understanding and discovery of Chalcone. Computed Properties of C15H12O
An efficient and sustainable protocol for the hydration of alkynes has been developed under metal/acid/catalyst/ ligand-free conditions in a water/ethyl lactate mixture. The hydrogen-bond network in the ethyl lactate and water mixture plays a crucial and decisive role in activating the alkynes for hydration to afford the corresponding methyl ketones. This strategy gives the Markovnikov (ketone) addition product selectively over other possible products. The essential role of hydrogen bonding has been confirmed by experimental and theoretical techniques. A probable mechanism has been suggested by various control tests. The efficacy of the method has been further explored for the competent production of value-added alpha,beta-unsaturated carbonyl compounds through the reaction of aldehydes with alkynes as ketonic surrogates. The environmentally benign hydration method takes place under mild conditions, has broad functional-group compatibility, and uses the ethyl lactate/water (1:3) medium as a green alternative in the absence of any hazardous, harmful, or expensive substances. (C) 2021 Elsevier B.V. All rights reserved.
Computed Properties of C15H12O. About Chalcone, If you have any questions, you can contact Dandia, A; Saini, P; Chithra, MJ; Vennapusa, SR; Parewa, V or concate me.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com