An article Synthesis and Structures of Arene Ruthenium (II)-NHC Complexes: Efficient Catalytic alpha-alkylation of ketones via Hydrogen Auto Transfer Reaction WOS:000454321800023 published article about N-HETEROCYCLIC CARBENE; ONE-POT SYNTHESIS; BORROWING HYDROGEN; SECONDARY ALCOHOLS; 2-AMINOBENZYL ALCOHOL; C-ALKYLATION; THIOCARBOXAMIDE COMPLEXES; TERTIARY-AMINES; BOND FORMATION; AMINATION in [Balamurugan, Gunasekaran; Balaji, Sundarraman; Ramesh, Rengan] Bharathidasan Univ, Sch Chem, Ctr Organometall Chem, Tiruchirappalli 620024, Tamil Nadu, India; [Bhuvanesh, Nattamai S. P.] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA in 2019.0, Cited 112.0. COA of Formula: C15H12O. The Name is Chalcone. Through research, I have a further understanding and discovery of 94-41-7
A panel of six new arene Ru (II)-NHC complexes 2a-f, (NHC = 1,3-diethyl-(5,6-dimethyl)benzimidazolin-2-ylidene 1a, 1,3-dicyclohexylmethyl-(5,6-dimethyl)benzimidazolin-2-ylidene 1b and 1,3-dibenzyl-(5,6-dimethyl)benzimidazolin-2-ylidene 1c) were synthesized from the transmetallation reaction of Ag-NHC with [(eta(6)-arene)RuCl2](2) and characterized. The ruthenium (II)-NHC complexes 2a-f were developed as effective catalysts for alpha-alkylation of ketones and synthesis of bioactive quinoline using primary/amino alcohols as coupling partners respectively. The reactions were performed with 0.5 mol% catalyst load in 8 h under aerobic condition and the maximum yield was up to 96%. Besides, the different alkyl wingtips on NHC and arene moieties were studied to differentiate the catalytic robustness of the complexes in the transformations.
COA of Formula: C15H12O. Bye, fridends, I hope you can learn more about C15H12O, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com