Tan, C; Liu, YG; Liu, XY; Jia, HX; Xu, K; Huang, SH; Wang, JW; Tan, JJ in [Tan, Chen; Liu, Xinyuan; Jia, Huanxin; Huang, Sihan; Wang, Jingwen; Tan, Jiajing] Beijing Univ Chem Technol, Coll Chem, Dept Organ Chem, Beijing 100029, Peoples R China; [Liu, Yongguo] BTBU, Beijing Key Lab Flavor Chem, Beijing 100048, Peoples R China; [Xu, Kun] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Henan, Peoples R China published Stereoselective synthesis of trans-aziridines via intramolecular oxidative C(sp(3))-H amination of beta-amino ketones in 2020.0, Cited 80.0. Safety of Chalcone. The Name is Chalcone. Through research, I have a further understanding and discovery of 94-41-7.
Aziridines are ubiquitous in bioactive molecules and often serve as key synthetic building blocks. We report herein an intramolecular KI/TBHP mediated oxidative dehydrogenative C(sp(3))-H amination reaction to synthesize a diverse array of trans-2,3-disubstituted aziridines in good yields under mild conditions. The synthetic utility of this protocol was further highlighted by a one-pot, two-step synthesis of unprotected aziridines.
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com