Recently I am researching about VISIBLE-LIGHT PHOTOREDOX; C-H ACTIVATION; GOLD CATALYSIS; DUAL GOLD; OXYARYLATION; INSERTION; SCOPE; TETRAHYDROFURANS; CARBOAMINATION; LIMITATIONS, Saw an article supported by the Centre National de la Recherche ScientifiqueCentre National de la Recherche Scientifique (CNRS); Universite de Toulouse; MESRI (Ministere de l’Enseignement Superieur, de la Recherche et de l’Innovation). Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Rigoulet, M; du Boullay, OT; Amgoune, A; Bourissou, D. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane. Category: thiazolidines
Heteroarylation of alkenes with aryl iodides was efficiently achieved with a (MeDalphos)AuCl complex through Au-I/Au-III catalysis. The possibility to combine oxidative addition of aryl iodides and yr-activation of alkenes at gold is demonstrated for the first time. The reaction is robust and general (> 30 examples including internal alkenes, 5-, 6-, and 7-membered rings). It is regioselective and leads exclusively to trans addition products. The (P,N) gold complex is most efficient with electron-rich aryl substrates, which are troublesome with alternative photoredox/oxidative approaches. In addition, it provides a very unusual switch in regioselectivity from 5-exo to 6-endo cyclization between the Z and E isomers of internal alkenols.
Welcome to talk about 78-39-7, If you have any questions, you can contact Rigoulet, M; du Boullay, OT; Amgoune, A; Bourissou, D or send Email.. Category: thiazolidines
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com