Recently I am researching about BOND FUNCTIONALIZATIONS; OXIDATIVE ARYLATION; AROMATIC KETONES; ARENES; AMIDATION; PALLADIUM; ACCESS; ALKENYLATION; ACTIVATION; ACTIVATION/ANNULATION, Saw an article supported by the SERB, Department of Science and Technology, New Delhi, IndiaDepartment of Science & Technology (India) [CRG/2018/000317]; IIT Kharagpur; DSTDepartment of Science & Technology (India) [SR/FST/CSII-026/2013]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Sk, MR; Maji, MS. The CAS is 94-41-7. Through research, I have a further understanding and discovery of Chalcone. COA of Formula: C15H12O
Weakly coordinating, ketone-directed C-H vinylation using vinyl acetate is reported here for a wide range of aromatic ketones such as acetophenones, diaryl ketones, chromones and biologically relevant chalcones under cost-effective and air-stable cobalt(iii)-catalysis. Regioselective, mono-vinylation occurs for challenging vinyl substitution-free styrenes in moderate to good yields, and this moiety has been used to synthesize functionalized indanone, alpha-naphthol and an advanced intermediate for bruguierol A synthesis. An acrylate-surrogate provided the corresponding alkenylated product under these vinylation conditions. Detailed mechanistic studies are carried out to support the proposed catalytic cycle.
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com